#include <avr/pgmspace.h>
const uint8_t mCylonScan[10][N_LED] PROGMEM = {
{255,0,0,0,0,0},
{0,255,0,0,0,0},
{0,0,255,0,0,0},
{0,0,0,255,0,0},
{0,0,0,0,255,0},
{0,0,0,0,0,255},
{0,0,0,0,255,0},
{0,0,0,255,0,0},
{0,0,255,0,0,0},
{0,255,0,0,0,0}
};
Then to access the data you just do the following (where 'i' and 'j' are loop variables):
data = pgm_read_byte(&(mCylonScan[i][j]));
See the AVR libc docs for more details.